The importance of the etching test
TMT bars are produced through a heat treatment process involving rapid quenching with water jets after hot rolling. This process cools the surface rapidly, forming a hardened layer of tempered martensite, while the inner core cools slowly, allowing it to remain soft and ductile, with a microstructure of ferrite and pearlite.
The etching test, also known as the "Ring Test," confirms the formation of this ideal composite structure.
Hard outer ring: A darker outer ring of tempered martensite is revealed upon etching.
Soft inner core: A lighter inner core of ferrite and pearlite should be visible.
Uniformity: The ring must be continuous, concentric, and of uniform thickness (typically 7–10% of the bar's diameter) to pass the test.
Sample preparation:
A small cross-sectional disc (25–30 mm thick) is cut from a representative TMT bar.One side of the disc is polished to a mirror-like finish using a series of progressively finer emery papers (e.g., grades 120 through 1500) and polishing equipment.Care must be taken to avoid overheating the sample, which can alter the microstructure. Coolants should be used during the cutting and polishing processes.
Etching:
The polished surface of the sample is dipped into a chemical etchant, most commonly Nital solution.Nital is a solution of nitric acid (5–10%) in ethyl alcohol (90–95%).The sample is submerged for a specific duration, which can vary depending on the steel and the etchant's concentration. A cloudy finish on the metal surface indicates the optimal etching time.
Rinsing and drying:After etching, the sample is immediately rinsed in water to stop the chemical reaction.It is then dried and prepared for examination.
Microstructural examination:The etched sample is examined under a metallurgical microscope at various magnifications (e.g., 50x to 1500x).
What the test reveals:The results of the etching test provide critical insights into the quality and heat treatment of the TMT bar.
Optimal microstructure: A clear, uniform, and concentric ring structure indicates that the bar was properly thermomechanically treated and possesses the desired combination of a strong, hard outer surface and a soft, ductile core.
Inadequate heat treatment: An improperly formed ring, a non-uniform structure, or a lack of a clear distinction between the core and the case may indicate manufacturing defects, such as improper quenching.
Mechanical properties: The microstructure directly correlates with the mechanical properties. An analysis can confirm that the bar has the necessary strength and ductility for construction applications. For instance, a very thick martensitic layer can make the bar brittle, while too much pearlite in the core can reduce strength